Chemoselective reduction of α,β-unsaturated aldehydes using an unsupported nanoporous gold catalyst.

نویسندگان

  • Balaram S Takale
  • Shanqiang Wang
  • Xuan Zhang
  • Xiujuan Feng
  • Xiaoqiang Yu
  • Tienan Jin
  • Ming Bao
  • Yoshinori Yamamoto
چکیده

The remarkable effect of an unsupported nanoporous gold catalyst (AuNPore) on chemoselective hydrogenation of α,β-unsaturated aldehydes using silane has been described. Enals can be reduced with excellent selectivity, giving the corresponding allylic alcohols in good to high chemical yields.

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عنوان ژورنال:
  • Chemical communications

دوره 50 92  شماره 

صفحات  -

تاریخ انتشار 2014